John F. Hartwig

Also affiliated with University of California System, NOAA Chemical Sciences Laboratory, University of California, Berkeley

ChemistryMaterials Science

Pilot corpus only

This score is computed over theSindex pilot corpus and does not cover the full scientific literature. Scores are relative to papers we have ingested — papers, authors, and institutions outside the pilot are not represented. Methodology.

Top 100%percentile

0Author DataRank

Indexed papers

0in pilot corpus

datarank_citation_only_1hop_v6· scope data_onlyMethodology

Papers

Driven by 76 papers. Top paper: “Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion”.

Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion

Chem(2020)10.1016/j.chempr.2020.11.020

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211 citations

Katerina G. Malollari, Adam Uliana, Daniel R. Sanchez, Phillip B. Messersmith, John F. Hartwig +1 more

Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions

Nature Chemistry(2020)10.1038/s41557-019-0409-4

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203 citations

Akito Ohgi, David W. Small, Kazuhiko Semba, Yoshiaki Nakao, John F. Hartwig +1 more

Diverse functionalization of strong alkyl C–H bonds by undirected borylation

Science(2020)10.1126/science.aba6146

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224 citations

Bo Su, Isaac Furay Yu, Christian Ehinger, Erik A. Romero, Sam He +2 more

Desymmetrization of difluoromethylene groups by C–F bond activation

Nature(2020)10.1038/s41586-020-2399-1

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134 citations

Jonathan Lee Yang, Willi M. Amberg, Nicholas B. Watkins, Natalie D. Wilkinson, John F. Hartwig +1 more

Catalytic asymmetric addition of an amine N–H bond across internal alkenes

Nature(2020)10.1038/s41586-020-2919-z

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115 citations

Senjie Ma, John F. Hartwig, Yumeng Xi

Oxalohydrazide Ligands for Copper‐Catalyzed C−O Coupling Reactions with High Turnover Numbers

Angewandte Chemie International Edition(2020)10.1002/anie.202015654

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91 citations

John F. Hartwig, Ritwika Ray

Mechanism of Ni-Catalyzed Oxidations of Unactivated C(sp3)–H Bonds

Journal of the American Chemical Society(2020)10.1021/jacs.0c09157

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79 citations

John F. Hartwig, Yehao Qiu

Palladium-Catalyzed Oxidation of β-C(sp3)–H Bonds of Primary Alkylamines through a Rare Four-Membered Palladacycle Intermediate

Journal of the American Chemical Society(2020)10.1021/jacs.0c01629

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58 citations

Ala Bunescu, Yehao Qiu, Stephan J. Zuend, Martin Ernst, John F. Hartwig +1 more

Copper-Catalyzed Defluorinative Borylation and Silylation of gem-Difluoroallyl Groups

Organic Letters(2020)10.1021/acs.orglett.0c02321

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34 citations

Jonathan Lee Yang, John F. Hartwig, Trevor W. Butcher

Iridium‐Catalyzed Silylation of Five‐Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl‐Imidazoline Ligand

Angewandte Chemie International Edition(2020)10.1002/anie.201916015

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53 citations

Camille Rubel, Е. В. Харитонова, John F. Hartwig, Caleb Karmel

Effect of Ligand Structure on the Electron Density and Activity of Iridium Catalysts for the Borylation of Alkanes

ACS Catalysis(2020)10.1021/acscatal.0c00152

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47 citations

Raphael J. Oeschger, John F. Hartwig, Matthew A. Larsen

Palladium-Catalyzed Oxidative Dehydrosilylation for Contra-Thermodynamic Olefin Isomerization

ACS Catalysis(2020)10.1021/acscatal.0c02697

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18 citations

Tyler Wills, Trevor W. Butcher, John F. Hartwig, Steven Hanna

Oxalohydrazide Ligands for Copper‐Catalyzed C−O Coupling Reactions with High Turnover Numbers

Angewandte Chemie(2020)10.1002/ange.202015654

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10 citations

John F. Hartwig, Ritwika Ray

Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds

Chemical Science(2020)10.1039/d0sc04402d

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11 citations

Sven Roediger, Víctor Laserna, John F. Hartwig, Casseday P. Richers

Cross‐Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate‐Determining Deprotonation of Bound Hydrazine

Angewandte Chemie(2020)10.1002/ange.202011161

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8 citations

Kyoungmin Choi, Stephan J. Zuend, Kailaskumar Borate, Harish M. Shinde, Roland Goetz +2 more

Ruthenium-Catalyzed Hydroamination of Unactivated Terminal Alkenes with Stoichiometric Amounts of Alkene and an Ammonia Surrogate by Sequential Oxidation and Reduction

Journal of the American Chemical Society(2020)10.1021/jacs.0c11043

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45 citations

Christopher K. Hill, Casey L. Olen, John F. Hartwig, Senjie Ma

Mechanism of the Iridium-Catalyzed Silylation of Aromatic C–H Bonds

Journal of the American Chemical Society(2020)10.1021/jacs.0c03301

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42 citations

John F. Hartwig, Caleb Karmel

Cross‐Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate‐Determining Deprotonation of Bound Hydrazine

Angewandte Chemie International Edition(2020)10.1002/anie.202011161

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31 citations

Kyoungmin Choi, Stephan J. Zuend, Kailaskumar Borate, Harish M. Shinde, Roland Goetz +2 more

Iridium‐Catalyzed Silylation of Five‐Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl‐Imidazoline Ligand

Angewandte Chemie(2020)10.1002/ange.201916015

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26 citations

Camille Rubel, Е. В. Харитонова, John F. Hartwig, Caleb Karmel

In Praise of Basic Research as a Vehicle to Practical Applications: Palladium‐Catalyzed Coupling to Form Carbon‐Nitrogen Bonds

Israel Journal of Chemistry(2020)10.1002/ijch.201900167

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26 citations

John F. Hartwig, Stephen L. Buchwald

Artificial Biosynthetic Pathway for an Unnatural Terpenoid with an Iridiumcontaining P450

ChemRxiv(2020)10.26434/chemrxiv.11955174

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8 citations

Zhennan Liu, Brandon J. Bloomer, Douglas S. Clark, Aindrila Mukhopadhyay, Jay D. Keasling +2 more

Artificial Biosynthetic Pathway for an Unnatural Terpenoid with an Iridiumcontaining P450

ChemRxiv(2020)10.26434/chemrxiv.11955174.v1

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7 citations

Zhennan Liu, Brandon J. Bloomer, Douglas S. Clark, Aindrila Mukhopadhyay, Jay D. Keasling +2 more

Mechanism of the Iridium-Catalyzed Silylation of Aromatic C–H Bonds

ChemRxiv(2020)10.26434/chemrxiv.12032619

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0 citations

John F. Hartwig, Caleb Karmel

Mechanism of the Iridium-Catalyzed Silylation of Aromatic C–H Bonds

ChemRxiv(2020)10.26434/chemrxiv.12032619.v1

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0 citations

John F. Hartwig, Caleb Karmel

Unnatural biosynthesis by an engineered microorganism with heterologously expressed natural enzymes and an artificial metalloenzyme

Nature Chemistry(2021)10.1038/s41557-021-00801-3

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118 citations

Zhennan Liu, Brandon J. Bloomer, Douglas S. Clark, Aindrila Mukhopadhyay, Jay D. Keasling +2 more

Abiotic reduction of ketones with silanes catalysed by carbonic anhydrase through an enzymatic zinc hydride

Nature Chemistry(2021)10.1038/s41557-020-00633-7

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76 citations

Jeeyoung Park, Yang Gu, Douglas S. Clark, John F. Hartwig, Pengfei Ji

Site-Selective Silver-Catalyzed C–H Bond Deuteration of Five-Membered Aromatic Heterocycles and Pharmaceuticals

ACS Catalysis(2021)10.1021/acscatal.0c04917

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73 citations

John F. Hartwig, Adrián Tlahuext-Aca

Site Selective Chlorination of C(sp3)−H Bonds Suitable for Late‐Stage Functionalization

Angewandte Chemie International Edition(2021)10.1002/anie.202016548

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56 citations

Manfred Keller, Zachary Herrera, John F. Hartwig, Alexander Fawcett

Direct Arylation of Simple Arenes with Aryl Bromides by Synergistic Silver and Palladium Catalysis

ACS Catalysis(2021)10.1021/acscatal.0c05254

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53 citations

Sarah Yunmi Lee, Shu Sakamoto, John F. Hartwig, Adrián Tlahuext-Aca

Mechanistic Investigation of the Iron-Catalyzed Azidation of Alkyl C(sp3)–H Bonds with Zhdankin’s λ3-Azidoiodane

Journal of the American Chemical Society(2021)10.1021/jacs.1c07330

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51 citations

Alexander Fawcett, Ruchira Chatterjee, John F. Hartwig, Craig S. Day

gem‐Difluoroallylation of Aryl Halides and Pseudo Halides with Difluoroallylboron Reagents in High Regioselectivity

Angewandte Chemie International Edition(2021)10.1002/anie.202111476

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31 citations

Trevor W. Butcher, Jonathan Lee Yang, John F. Hartwig, Shu Sakamoto

Direct Observation of Diastereomeric α-C-Bound Enolates during Enantioselective α-Arylations: Synthesis, Characterization, and Reactivity of Arylpalladium Fluorooxindole Complexes

Journal of the American Chemical Society(2021)10.1021/jacs.1c05346

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28 citations

John F. Hartwig, Eric D. Kalkman

Unnatural Biosynthesis by an Engineered Microorganism with Heterologously Expressed Natural Enzymes and an Artificial Metalloenzyme

Research Square(2021)10.21203/rs.3.rs-130318/v1

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7 citations

Zhennan Liu, Brandon J. Bloomer, Douglas S. Clark, Aindrila Mukhopadhyay, Jay D. Keasling +2 more

Catalytic deconstruction of waste polyethylene with ethylene to form propylene

Science(2022)10.1126/science.add1088

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398 citations

Steven Hanna, Jake X. Shi, Ji Yang, Nicodemo R. Ciccia, Liang Qi +7 more

Enantioselective hydroamination of unactivated terminal alkenes

Chem(2022)10.1016/j.chempr.2021.12.005

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56 citations

Yumeng Xi, Haoyu Fan, Sven Roediger, John F. Hartwig, Senjie Ma

Assembly and Evolution of Artificial Metalloenzymes within E. coli Nissle 1917 for Enantioselective and Site-Selective Functionalization of C─H and C═C Bonds

Journal of the American Chemical Society(2022)10.1021/jacs.1c10975

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41 citations

Jing Huang, Yang Gu, Douglas S. Clark, Aindrila Mukhopadhyay, Jay D. Keasling +2 more

Palladium‐Catalyzed Aryldifluoromethylation of Aryl Halides with Aryldifluoromethyl Trimethylsilanes

Angewandte Chemie International Edition(2022)10.1002/anie.202208204

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24 citations

Michael G. Mormino, Eric D. Kalkman, John Park, John F. Hartwig, Kyoungmin Choi

Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydroboration and Dehydroboration

Organic Letters(2022)10.1021/acs.orglett.1c03124

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9 citations

Brandon J. Bloomer, Nicodemo R. Ciccia, Trevor W. Butcher, Richard J. Conk, John F. Hartwig +1 more

A Hybrid Machine-Learning Approach to Predict the Iridium-Catalyzed Borylation of C–H Bonds

ChemRxiv(2022)10.26434/chemrxiv-2022-7qw68

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7 citations

Masha Elkin, Golsa Gheibi, Magnus J. Johansson, Christian Sköld, Per‐Ola Norrby +2 more

Catalytic, Undirected Borylation of Tertiary C–H Bonds in Bicyclo[1.1.1]pentanes and Bicyclo[2.1.1]hexanes

ChemRxiv(2022)10.26434/chemrxiv-2022-pzs6m

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4 citations

Jenna L. Manske, Alejandro Diéguez-vázquez, Antonio Misale, Alexander Pashenko, Sergey V. Ryabukhin +3 more

Diverse functional polyethylenes by catalytic amination

Science(2023)10.1126/science.adg6093

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116 citations

Jake X. Shi, Subhajit Pal, Mutian Hua, Katerina G. Malollari, Carlos Lizandara‐Pueyo +6 more

Catalytic undirected borylation of tertiary C–H bonds in bicyclo[1.1.1]pentanes and bicyclo[2.1.1]hexanes

Nature Chemistry(2023)10.1038/s41557-023-01159-4

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107 citations

Jenna L. Manske, A. Dieguez-Vazquez, Antonio Misale, Alexander Pashenko, Pavel K. Mykhailiuk +4 more

Oxidative addition of an alkyl halide to form a stable Cu(III) product

Science(2023)10.1126/science.adg9232

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101 citations

Yuli Li, Jian Wu, Xiao‐Song Xue, John F. Hartwig, Qilong Shen +1 more

Progression of Hydroamination Catalyzed by Late Transition-Metal Complexes from Activated to Unactivated Alkenes

Accounts of Chemical Research(2023)10.1021/acs.accounts.3c00141

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89 citations

John F. Hartwig, Senjie Ma

Cross-coupling by a noncanonical mechanism involving the addition of aryl halide to Cu(II)

Science(2023)10.1126/science.adi9226

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73 citations

Eva Lin, Qin-An Huang, Isaac Furay Yu, Guodong Rao, Lizhi Tao +6 more

Complete integration of carbene-transfer chemistry into biosynthesis

Nature(2023)10.1038/s41586-023-06027-2

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67 citations

Andrew F. G. Quest, Pablo Cruz‐Morales, Kai Deng, J.H. Pereira, Devon Van Cura +13 more

Hybrid Machine Learning Approach to Predict the Site Selectivity of Iridium-Catalyzed Arene Borylation

Journal of the American Chemical Society(2023)10.1021/jacs.3c04986

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63 citations

Masha Elkin, Golsa Gheibi, Magnus J. Johansson, Christian Sköld, Per‐Ola Norrby +2 more

Discovery of the Azaserine Biosynthetic Pathway Uncovers a Biological Route for α‐Diazoester Production

Angewandte Chemie International Edition(2023)10.1002/anie.202304646

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50 citations

Tai L. Ng, Jing Huang, Harry H. Hager, John F. Hartwig, Jay D. Keasling +2 more

Remote Hydroamination of Disubstituted Alkenes by a Combination of Isomerization and Regioselective N–H Addition

Journal of the American Chemical Society(2023)10.1021/jacs.2c13054

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33 citations

Haoyu Fan, Craig S. Day, Yumeng Xi, John F. Hartwig, Senjie Ma

Mechanistic and structural characterization of an iridium-containing cytochrome reveals kinetically relevant cofactor dynamics

Nature Catalysis(2023)10.1038/s41929-022-00899-9

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24 citations

Sean N. Natoli, Marc Garcia‐Borràs, J.H. Pereira, Derek B. Hu, Paul D. Adams +4 more

Iridium-Catalyzed, Site-Selective Silylation of Secondary C(sp3)–H Bonds in Secondary Alcohols and Ketones

Journal of the American Chemical Society(2023)10.1021/jacs.3c03127

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15 citations

Bo Su, Makoto Yoritate, Jake X. Shi, John F. Hartwig, Jake W. Wilson

Transition-State Stabilization by Secondary Orbital Interactions between Fluoroalkyl Ligands and Palladium During Reductive Elimination from Palladium(aryl)(fluoroalkyl) Complexes

ACS Catalysis(2023)10.1021/acscatal.3c02648

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11 citations

Yehao Qiu, John F. Hartwig, Eric D. Kalkman

A Hybrid Machine-Learning Approach to Predict the Site Selectivity of Iridium-Catalyzed Arene Borylation

ChemRxiv(2023)10.26434/chemrxiv-2022-7qw68-v2

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6 citations

Masha Elkin, Golsa Gheibi, Magnus J. Johansson, Christian Sköld, Per‐Ola Norrby +2 more

Mechanistic insights into the origins of selectivity in a Cu-catalyzed C–H amidation reaction

ChemRxiv(2023)10.26434/chemrxiv-2023-cn8g7

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1 citations

Nicodemo R. Ciccia, Yifan Guo, John F. Hartwig, Martin Head‐Gordon, Alistair J. Sterling

Discovery of the Azaserine Biosynthetic Pathway Uncovers a Biological Route for α‐Diazoester Production

Angewandte Chemie(2023)10.1002/ange.202304646

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0 citations

Tai L. Ng, Jing Huang, Harry H. Hager, John F. Hartwig, Jay D. Keasling +2 more

Deconvolution and Analysis of 1H NMR Spectra of Crude Reaction Mixtures

ChemRxiv(2023)10.26434/chemrxiv-2023-g82z3

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0 citations

Masha Elkin, Connor P. Delaney, John F. Hartwig, Kristin A. Persson, Maxwell C. Venetos

2-Aminophenanthrolines Enable the Mild, Undirected Borylation of Alkyl C–H Bonds

ChemRxiv(2023)10.26434/chemrxiv-2023-0l7fm

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0 citations

Kyan A. D’Angelo, Ángel D. Hernández-Mejías, Nanrun Cheng, John F. Hartwig, Isaac Furay Yu

Mapping the mechanisms of oxidative addition in cross-coupling reactions catalysed by phosphine-ligated Ni(0)

Nature Chemistry(2024)10.1038/s41557-024-01451-x

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42 citations

John F. Hartwig, Christina N. Pierson

Palladium-Catalyzed Amination of Aryl Halides with Aqueous Ammonia and Hydroxide Base Enabled by Ligand Development

Journal of the American Chemical Society(2024)10.1021/jacs.4c05768

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32 citations

John N. Brunn, Kailaskumar Borate, Rahul D. Kaduskar, Carlos Lizandara‐Pueyo, Harish M. Shinde +3 more

2-Aminophenanthroline Ligands Enable Mild, Undirected, Iridium-Catalyzed Borylation of Alkyl C–H Bonds

Journal of the American Chemical Society(2024)10.1021/jacs.3c12981

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30 citations

Kyan A. D’Angelo, Ángel D. Hernández-Mejías, Nanrun Cheng, John F. Hartwig, Isaac Furay Yu

Polymers from Plant Oils Linked by Siloxane Bonds for Programmed Depolymerization

Journal of the American Chemical Society(2024)10.1021/jacs.4c01982

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17 citations

Jake X. Shi, Eun-Hye Kang, Taylor F. Nelson, Michael Sander, Kristopher McNeill +2 more

Asymmetric Amination of Unstrained C(sp3)–C(sp3) Bonds

Journal of the American Chemical Society(2024)10.1021/jacs.4c11802

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17 citations

Ye‐Wei Chen, Yuanxiang Yang, John F. Hartwig, Zhi‐Tao He, Yang Liu

An Air-Stable, Single-Component Iridium Precatalyst for the Borylation of C–H Bonds on Large to Miniaturized Scales

Journal of the American Chemical Society(2024)10.1021/jacs.4c12333

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15 citations

Chris La, Brian Kotecki, Jake W. Wilson, Caleb Karmel, Rafal Swiatowiec +4 more

Carbonic Anhydrase Variants Catalyze the Reduction of Dialkyl Ketones with High Enantioselectivity

Angewandte Chemie International Edition(2024)10.1002/anie.202407111

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17 citations

Colby S. Kayrouz, Eli McAmis, Douglas S. Clark, John F. Hartwig, Reichi Chen

Deconvolution and Analysis of the 1 H NMR Spectra of Crude Reaction Mixtures

Journal of Chemical Information and Modeling(2024)10.1021/acs.jcim.3c01864

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14 citations

Masha Elkin, Connor P. Delaney, John F. Hartwig, Kristin A. Persson, Maxwell C. Venetos

Convergent synthesis and protein binding of vicinal difluorides by stereodivergent C–C bond formation

Chem(2024)10.1016/j.chempr.2024.08.024

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14 citations

Vienna C.J.X. Thomas, Tommaso Fantoni, Reichi Chen, X. S. Jiang, Zhi‐Tao He +4 more

Substitution, Elimination, and Integration of Methyl Groups in Terpenes Initiated by C–H Bond Functionalization

ACS Central Science(2024)10.1021/acscentsci.4c01108

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11 citations

Richard T. Wetterer, Rashad R. Karimov, M. Kojima, Max Surke, Inmaculada Martín‐Torres +4 more

Catalytic undirected methylation of unactivated C(sp3)−H bonds suitable for complex molecules

Nature Communications(2024)10.1038/s41467-024-52245-1

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9 citations

Yi Cheng Kang, John F. Hartwig, Jin-Fay Tan

Carbonic Anhydrase Variants Catalyze the Reduction of Dialkyl Ketones with High Enantioselectivity

Angewandte Chemie(2024)10.1002/ange.202407111

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0 citations

Colby S. Kayrouz, Eli McAmis, Douglas S. Clark, John F. Hartwig, Reichi Chen

Backbone editing and deconstruction of polyethylene by Beckmann rearrangement and hydrogenolysis

Chemical Science(2025)10.1039/d5sc02684a

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16 citations

Diane D. Kim, Nicodemo R. Ciccia, Pierre Lahaie-Boivin, John F. Hartwig, Jake X. Shi

Efficient Aminations of Aryl Halides by a Cu(II) Catalyst

Journal of the American Chemical Society(2025)10.1021/jacs.5c05210

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13 citations

Teresa Horak, Willi M. Amberg, Ritwika Ray, Guodong Rao, Timothy M. Pinkhassik +6 more

Catalytic Borylation of Poly(vinyl chloride) Produces Adhesive Materials

Journal of the American Chemical Society(2025)10.1021/jacs.5c08083

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8 citations

Nannan Sun, Nicodemo R. Ciccia, Isaac Furay Yu, Brett A. Helms, John F. Hartwig +1 more

Electronic Activation Enables the Borylation of Alkyl C–H Bonds in Saturated Nitrogen Heterocycles

Journal of the American Chemical Society(2025)10.1021/jacs.5c15431

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8 citations

R.L. Zheng, Isaac Furay Yu, Melody J. Tang, Chris La, Richard T. Wetterer +2 more

Enantioselective Synthesis of Spirocyclic Nitrogen-Containing Heterocycles Catalyzed by an Iridium-Containing Cytochrome

Journal of the American Chemical Society(2025)10.1021/jacs.5c06239

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3 citations

Brandon J. Bloomer, John N. Brunn, Andrew P. Quest, Sukriyo Chakraborty, Joseph E. Schneider +3 more

Late‐Stage Oxidation of C( sp 3 )─H Bonds with High Efficiency and Alkyl Group Dihydroxylation of Complex Molecules

Angewandte Chemie International Edition(2025)10.1002/anie.202513418

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2 citations

Dmitriy M. Volochnyuk, Sergey V. Ryabukhin, John F. Hartwig, Yi Cheng Kang

Late‐Stage Oxidation of C( sp 3 )─H Bonds with High Efficiency and Alkyl Group Dihydroxylation of Complex Molecules

Angewandte Chemie(2025)10.1002/ange.202513418

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0 citations

Dmitriy M. Volochnyuk, Sergey V. Ryabukhin, John F. Hartwig, Yi Cheng Kang