Matthew S. Sigman

Materials Science

Pilot corpus only

This score is computed over theSindex pilot corpus and does not cover the full scientific literature. Scores are relative to papers we have ingested — papers, authors, and institutions outside the pilot are not represented. Methodology.

Top 100%percentile

0Author DataRank

Indexed papers

0in pilot corpus

datarank_citation_only_1hop_v6· scope data_onlyMethodology

Papers

Driven by 69 papers. Top paper: “Rapid prediction of conformationally-dependent DFT-level descriptors using graph neural networks for carboxylic acids and alkyl amines”.

Rapid prediction of conformationally-dependent DFT-level descriptors using graph neural networks for carboxylic acids and alkyl amines

Digital Discovery(2024)10.1039/d4dd00284a

N/A

0.564DataRank · unranked

17 citations

Melissa A. Hardy, Shree Sowndarya S. V., Keir Adams, Connor W. Coley, Robert S. Paton +2 more

Data Science-Driven Analysis of Substrate-Permissive Diketopiperazine Reverse Prenyltransferase NotF: Applications in Protein Engineering and Cascade Biocatalytic Synthesis of (−)-Eurotiumin A

Journal of the American Chemical Society(2022)10.1021/jacs.2c06631

N/A

0.550DataRank · unranked

38 citations

Vikram V. Shende, Autumn R. Flynn, Qingyun Dan, Ying Ye, Janet L. Smith +4 more

Cobalt-Electrocatalytic Hydrogen Atom Transfer for Functionalization of Unsaturated C–C Bonds

ChemRxiv(2021)10.26434/chemrxiv-2021-b34zl

N/A

0.241DataRank · unranked

4 citations

Samer Gnaim, Adriano Bauer, Haijun Zhang, Longrui Chen, Cara Gannet +17 more

Identifying structure-function relationships to modulate crossover in nonaqueous redox flow batteries

Journal of Materials Chemistry A(2023)10.1039/d3ta02633g

N/A

0.241DataRank · unranked

4 citations

Autumn R. Flynn, Matthew S. Sigman, Melanie S. Sanford, Brianna Jett

DNA-Scaffolded Ultrahigh-Throughput Reaction Screening

ChemRxiv(2025)10.26434/chemrxiv-2025-lm981

N/A

0.104DataRank · unranked

1 citations

Edward B. Pimentel, Beck Miller, Daniel J. Nesbitt, Justice L. Merrifield, Ethan M. Hartman +6 more

Analyzing Mechanisms in Co(I) Redox Catalysis Using a Pattern Recognition Platform

ChemRxiv(2020)10.26434/chemrxiv.13017161.v1

N/A

0DataRank · unranked

1 citations

Christopher Sandford, Shelley D. Minteer, Matthew S. Sigman, Tianhua Tang

Data Science Meets Physical Organic Chemistry

Accounts of Chemical Research(2021)10.1021/acs.accounts.1c00285

N/A

0DataRank · unranked

117 citations

Cian Kingston, F. Dean Toste, Matthew S. Sigman, Jennifer M. Crawford

Nickel-catalyzed asymmetric reductive cross-coupling of α-chloroesters with (hetero)aryl iodides

Chemical Science(2021)10.1039/d1sc00822f

N/A

0DataRank · unranked

66 citations

Sara E. Dibrell, Caitlin R. Lacker, Adam R. Pancoast, Kelsey E. Poremba, Leah Cleary +3 more

Interrogation of 2,2′-Bipyrimidines as Low-Potential Two-Electron Electrolytes

Journal of the American Chemical Society(2021)10.1021/jacs.0c11267

N/A

0DataRank · unranked

46 citations

Adam R. Pancoast, Matthew S. Sigman, Jeremy Griffin

A Data-Driven Approach to the Development and Understanding of Chiroptical Sensors for Alcohols with Remote γ-Stereocenters

Journal of the American Chemical Society(2021)10.1021/jacs.1c09443

N/A

0DataRank · unranked

26 citations

Eric V. Anslyn, Matthew S. Sigman, Jordan J. Dotson

Analyzing mechanisms in Co( i ) redox catalysis using a pattern recognition platform

Chemical Science(2021)10.1039/d0sc06725c

N/A

0DataRank · unranked

21 citations

Christopher Sandford, Shelley D. Minteer, Matthew S. Sigman, Tianhua Tang

Rate Profiling the Impact of Remote Functional Groups on the Redox-Relay Heck Reaction

Organic Letters(2021)10.1021/acs.orglett.1c00450

N/A

0DataRank · unranked

11 citations

Sean P. Ross, Matthew S. Sigman, Samantha L. Kraus

Cobalt-Electrocatalytic Hydrogen Atom Transfer for Functionalization of Unsaturated C–C Bonds

(2021)10.33774/chemrxiv-2021-b34zl

N/A

0DataRank · unranked

4 citations

Samer Gnaim, Adriano Bauer, Haijun Zhang, Longrui Chen, Cara Gannet +17 more

Workflow for Biocatalytic Reaction Performance Prediction and Analysis

ChemRxiv(2021)10.26434/chemrxiv-2021-9gd5m

N/A

0DataRank · unranked

4 citations

Autumn R. Flynn, Bryce T. Nicholls, Daria Grosheva, Todd K. Hyster, Matthew S. Sigman +1 more

Electrochemical cobalt-catalyzed selective carboxylation of benzyl halides with CO2 enabled by low-coordinate cobalt electrocatalysts

(2021)10.33774/chemrxiv-2021-thftp

N/A

0DataRank · unranked

3 citations

Mayank Tanwar, Andrew D. Pendergast, Sagar Udyavara, Wesley Beck, Ryan Smith +9 more

Electrochemical cobalt-catalyzed selective carboxylation of benzyl halides with CO2 enabled by low-coordinate cobalt electrocatalysts

ChemRxiv(2021)10.26434/chemrxiv-2021-thftp

N/A

0DataRank · unranked

1 citations

Mayank Tanwar, Andrew D. Pendergast, Sagar Udyavara, Wesley Beck, Ryan E. Smith +9 more

An Explosophore-Based Approach Towards the Prediction of Energetic Material Sensitivity Properties

ChemRxiv(2021)10.26434/chemrxiv-2021-16f6w-v2

N/A

0DataRank · unranked

1 citations

Jonathan M. Meinhardt, Julie L. Hofstra Wahlman, Matthew S. Sigman, Song Lin, Jonas Rein

An Explosophore-Based Approach Towards the Prediction of Energetic Material Sensitivity Properties

ChemRxiv(2021)10.26434/chemrxiv-2021-16f6w

N/A

0DataRank · unranked

1 citations

Jonathan M. Meinhardt, Julie L. Hofstra Wahlman, Matthew S. Sigman, Song Lin, Jonas Rein

An Explosophore-Based Approach Towards the Prediction of Energetic Material Sensitivity Properties

(2021)10.33774/chemrxiv-2021-16f6w

N/A

0DataRank · unranked

1 citations

Jonathan M. Meinhardt, Julie L. Hofstra Wahlman, Matthew S. Sigman, Song Lin, Jonas Rein

An Explosophore-Based Approach Towards the Prediction of Energetic Material Sensitivity Properties

(2021)10.33774/chemrxiv-2021-16f6w-v2

N/A

0DataRank · unranked

0 citations

Jonathan M. Meinhardt, Julie L. Hofstra Wahlman, Matthew S. Sigman, Song Lin, Jonas Rein

A Data-Driven Approach to the Development and Understanding of Chiroptical Sensors for Alcohols with Remote γ-Stereocenters

(2021)10.33774/chemrxiv-2021-zqpq8

N/A

0DataRank · unranked

0 citations

Eric V. Anslyn, Matthew S. Sigman, Jordan J. Dotson

Structural and Data Science-Driven Analysis to Assess Substrate Specificity of Diketopiperazine Reverse Prenyltransferase NotF: Cascade Biocatalytic Synthesis of (–)-Eurotiumin A

(2021)10.33774/chemrxiv-2021-gmv5j

N/A

0DataRank · unranked

0 citations

Vikram V. Shende, Autumn R. Flynn, Qingyun Dan, Ying Ye, Janet L. Smith +4 more

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling of a-Chloroesters with (Hetero)Aryl Iodides

ChemRxiv(2021)10.26434/chemrxiv.13474638.v1

N/A

0DataRank · unranked

0 citations

Sara E. Dibrell, Caitlin R. Lacker, Adam R. Pancoast, Kelsey E. Poremba, Leah Cleary +3 more

A Data-Driven Approach to the Development and Understanding of Chiroptical Sensors for Alcohols with Remote γ-Stereocenters

ChemRxiv(2021)10.26434/chemrxiv-2021-zqpq8

N/A

0DataRank · unranked

0 citations

Eric V. Anslyn, Matthew S. Sigman, Jordan J. Dotson

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling of a-Chloroesters with (Hetero)Aryl Iodides

ChemRxiv(2021)10.26434/chemrxiv.13474638

N/A

0DataRank · unranked

0 citations

Sara E. Dibrell, Caitlin R. Lacker, Adam R. Pancoast, Kelsey E. Poremba, Leah Cleary +3 more

Structural and Data Science-Driven Analysis to Assess Substrate Specificity of Diketopiperazine Reverse Prenyltransferase NotF: Cascade Biocatalytic Synthesis of (–)-Eurotiumin A

ChemRxiv(2021)10.26434/chemrxiv-2021-gmv5j

N/A

0DataRank · unranked

0 citations

Vikram V. Shende, Autumn R. Flynn, Qingyun Dan, Ying Ye, Janet L. Smith +4 more

N-Ammonium Ylide Mediators for Selective Electrochemical C–H Oxidation

ChemRxiv(2021)10.26434/chemrxiv.14054783

N/A

0DataRank · unranked

0 citations

Yu Kawamata, Michael Meanwell, Rafael Navrátil, Debora Chiodi, Ethan Carlson +19 more

Data-Driven Multi-Objective Optimization Tactics for Catalytic Asymmetric Reactions Using Bisphosphine Ligands

Journal of the American Chemical Society(2022)10.1021/jacs.2c08513

N/A

0DataRank · unranked

111 citations

Lucy van Dijk, Jacob C. Timmerman, Samantha Grosslight, Richard C. Walroth, Francis Gosselin +4 more

Predicting relative efficiency of amide bond formation using multivariate linear regression

Proceedings of the National Academy of Sciences(2022)10.1073/pnas.2118451119

N/A

0DataRank · unranked

48 citations

Adam E. Goetz, Ana Bahamonde, J. Christopher McWilliams, Matthew S. Sigman, Brittany C. Haas

Noncovalent Stabilization of Radical Intermediates in the Enantioselective Hydroamination of Alkenes with Sulfonamides

Journal of the American Chemical Society(2022)10.1021/jacs.2c07099

N/A

0DataRank · unranked

34 citations

Jacob Werth, Casey B. Roos, Andrew J. Bendelsmith, Matthew S. Sigman, Robert R. Knowles +1 more

Exploring Structure–Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques

ACS Catalysis(2022)10.1021/acscatal.2c04824

N/A

0DataRank · unranked

18 citations

Julie L. Hofstra Wahlman, Jacquelyne A. Read, Jacob Werth, Eric N. Jacobsen, Matthew S. Sigman +1 more

Comparing Halogen Atom Abstraction Kinetics for Mn(I), Fe(I), Co(I), and Ni(I) Complexes by Combining Electroanalytical and Statistical Modeling

European Journal of Organic Chemistry(2022)10.1002/ejoc.202200064

N/A

0DataRank · unranked

6 citations

Nathan C. Friede, Shelley D. Minteer, Matthew S. Sigman, Tianhua Tang

Small Molecule Properties Define Partitioning into Biomolecular Condensates

bioRxiv (Cold Spring Harbor Laboratory)(2022)10.1101/2022.12.19.521099

N/A

0DataRank · unranked

24 citations

Hanna D. Clements, Hamid Baniasadi, Andrew S. Lyon, Matthew S. Sigman, Michael K. Rosen +1 more

Data-driven multi-objective optimization tactics for catalytic asymmetric reactions

ChemRxiv(2022)10.26434/chemrxiv-2022-qqxd1

N/A

0DataRank · unranked

2 citations

Lucy van Dijk, Jacob C. Timmerman, Samantha Grosslight, Richard C. Walroth, Kurt Püntener +4 more

Interrogating the Mechanistic Features of Ni(I)-Mediated Aryl Iodide Oxidative Addition Using Electroanalytical and Statistical Modeling Techniques

Journal of the American Chemical Society(2023)10.1021/jacs.3c01726

N/A

0DataRank · unranked

78 citations

Avijit Hazra, Daniel S. Min, Wendy L. Williams, E. Jones, Abigail G. Doyle +2 more

Data science enables the development of a new class of chiral phosphoric acid catalysts

Chem(2023)10.1016/j.chempr.2023.02.020

N/A

0DataRank · unranked

43 citations

Caroline Rouget-Virbel, Julie L. Hofstra Wahlman, René Rahimoff, Jennifer M. Crawford, Abby Medlin +6 more

Using Data Science for Mechanistic Insights and Selectivity Predictions in a Non-Natural Biocatalytic Reaction

Journal of the American Chemical Society(2023)10.1021/jacs.3c03639

N/A

0DataRank · unranked

35 citations

Autumn R. Flynn, Bryce T. Nicholls, Daria Grosheva, Sarah J. Lefave, Morgan T. Merriman +3 more

An Asymmetric Aromatic Finkelstein Reaction: A Platform for Remote Diarylmethane Desymmetrization

Journal of the American Chemical Society(2023)10.1021/jacs.3c08727

N/A

0DataRank · unranked

17 citations

Tyler E. Myers, Lucas J. Karas, Melissa A. Hardy, Brandon Q. Mercado, Matthew S. Sigman +2 more

Data science enabled discovery of a highly soluble 2,2′-bipyrimidine anolyte for application in a flow battery

Chemical Science(2023)10.1039/d3sc04084d

N/A

0DataRank · unranked

10 citations

Sara L. McCormack, Shelby Galinat, Ryan Walser-Kuntz, Brianna Jett, Melanie S. Sanford +2 more

14N to 15N Isotopic Exchange of Nitrogen Heteroaromatics through Skeletal Editing

ChemRxiv(2023)10.26434/chemrxiv-2023-30dtw

N/A

0DataRank · unranked

4 citations

Samantha L. Kraus, Lucas J. Karas, Filippo Carpaneto, Raffeal Bennett, Matthew S. Sigman +3 more

Predicting Success in Cu-Catalyzed C–N Coupling Reactions using Data Science

ChemRxiv(2023)10.26434/chemrxiv-2023-f50w6

N/A

0DataRank · unranked

2 citations

Lucas J. Karas, David B. Vogt, Emmanuel Odogwu, Jennifer M. Elward, Jennifer M. Crawford +3 more

An Asymmetric Aromatic Finkelstein Reaction: A Platform for Remote Diarylmethane Desymmetrization

ChemRxiv(2023)10.26434/chemrxiv-2023-c9s4p

N/A

0DataRank · unranked

1 citations

Tyler Myers, Lucas J. Karas, Melissa Hardy, Brandon Q. Mercado, Matthew S. Sigman +2 more

14 N to 15 N Isotopic Exchange of Nitrogen Heteroaromatics through Skeletal Editing

Journal of the American Chemical Society(2024)10.1021/jacs.3c11515

N/A

0DataRank · unranked

93 citations

Samantha L. Kraus, Lucas J. Karas, Filippo Carpaneto, Raffeal Bennett, Matthew S. Sigman +3 more

Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation

Journal of the American Chemical Society(2024)10.1021/jacs.4c00374

N/A

0DataRank · unranked

51 citations

Ngiap‐Kie Lim, Janis Jermaks, Eden Gaster, Melody C. Guo, Thomas C. Malig +7 more

Development of a Deactivation-Resistant Dialkylbiarylphosphine Ligand for Pd-Catalyzed Arylation of Secondary Amines

Journal of the American Chemical Society(2024)10.1021/jacs.4c09667

N/A

0DataRank · unranked

31 citations

Elaine C. Reichert, James R. Howard, Ellyn Peters, Cecilia Liu, Matthew S. Sigman +2 more

Computational Library Enables Pattern Recognition of Noncovalent Interactions and Application as a Modern Linear Free Energy Relationship

The Journal of Organic Chemistry(2024)10.1021/acs.joc.4c01790

N/A

0DataRank · unranked

12 citations

Tyler E. Ball, Beck Miller, Eric N. Jacobsen, Matthew S. Sigman, Jacquelyne A. Read

Modular synthesis of aryl amines from 3-alkynyl-2-pyrones

Chemical Science(2024)10.1039/d4sc04885g

N/A

0DataRank · unranked

6 citations

Louis de Lescure, Melissa A. Hardy, Jin Tan, Matthew S. Sigman, Robert S. Paton +2 more

Rapid Prediction of Conformationally-Dependent DFT-Level Descriptors using Graph Neural Networks for Carboxylic Acids and Alkyl Amines

ChemRxiv(2024)10.26434/chemrxiv-2024-m5bpn

N/A

0DataRank · unranked

4 citations

Melissa A. Hardy, Shree Sowndarya S. V., Keir Adams, Connor W. Coley, Robert S. Paton +2 more

Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation

ChemRxiv(2024)10.26434/chemrxiv-2024-qm8jp

N/A

0DataRank · unranked

0 citations

Ngiap‐Kie Lim, Janis Jermaks, Eden Gaster, Melody C. Guo, Thomas C. Malig +7 more

Ni-Catalyzed Enantioselective Desymmetrization: Development of Divergent Acyl and Decarbonylative Cross-Coupling Reactions

ChemRxiv(2024)10.26434/chemrxiv-2024-3r6z4

N/A

0DataRank · unranked

0 citations

Alexander Shimozono, Avijit Hazra, Sven C. Richter, Zhengjia Tong, Neil F. Langille +5 more

Development of a Simple Thioetherification of Heteroarene Electrophiles with Broad Scope via a Proton Transfer Dual Ioni-zation Mechanism

ChemRxiv(2024)10.26434/chemrxiv-2023-0bjgp-v2

N/A

0DataRank · unranked

0 citations

Jeremy Henle, Shashank Shekhar, Cassie Yang, Yong Zhou, Amanda L. Wall +7 more

Interrogation of Enantioselectivity in the Photomediated Ring Contractions of Saturated Heterocycles

Journal of the American Chemical Society(2025)10.1021/jacs.4c13999

N/A

0DataRank · unranked

19 citations

Jordan P. Liles, Michaelyn C. Lux, Hojoon Park, Justin Jurczyk, Yasuki Soda +4 more

Understanding Catalytic Enantioselective C–H Bond Oxidation at Nonactivated Methylenes Through Predictive Statistical Modeling Analysis

ACS Catalysis(2025)10.1021/acscatal.4c05659

N/A

0DataRank · unranked

13 citations

Andrea Palone, Jordan P. Liles, Natalie P. Romer, Jacquelyne A. Read, Josep M. Luis +4 more

Data Science-Guided Development of Deoxyfluorination Reagents with Enhanced Reactivity, Practicality, and Safety

Journal of the American Chemical Society(2025)10.1021/jacs.5c07548

N/A

0DataRank · unranked

11 citations

Natalie P. Romer, Julie A. Deichert, Lady Mae Alabanza, Shivaani S. Gandhi, Giselle Z. Brown +7 more

Considerations in Pursuing Reaction Scope Generality

Angewandte Chemie International Edition(2025)10.1002/anie.202511091

N/A

0DataRank · unranked

8 citations

Juliana A. Dantas, Song Lin, Abigail G. Doyle, Matthew S. Sigman, Samson B. Zacate

Development of a Thioetherification of Heteroarene Electrophiles with Broad Scope via a Proton Transfer Dual Ionization Mechanism

Journal of the American Chemical Society(2025)10.1021/jacs.4c18304

N/A

0DataRank · unranked

7 citations

Maike Eckhoff, Jeremy Henle, Anna V. Bay, Rafal Swiatowiec, Shashank Shekhar +7 more

A Data Science-Guided Approach for the Development of Nickel-Catalyzed Homo-Diels–Alder Reactions

Journal of the American Chemical Society(2025)10.1021/jacs.5c09948

N/A

0DataRank · unranked

3 citations

Cedric Lozano, Morgan T. Merriman, P.F. Oblad, Matthew S. Sigman, Sarah E. Reisman +1 more

Considerations in Pursuing Reaction Scope Generality

Angewandte Chemie(2025)10.1002/ange.202511091

N/A

0DataRank · unranked

1 citations

Juliana A. Dantas, Song Lin, Abigail G. Doyle, Matthew S. Sigman, Samson B. Zacate

Macrocycles of Saxitoxin: Insights into the Structure of Zetekitoxin AB

ChemBioChem(2025)10.1002/cbic.202500170

N/A

0DataRank · unranked

3 citations

Srinivas R. Paladugu, Jordan P. Liles, Manju Karthikeyan, Kevin Chase, Shrinivasan Raghuraman +3 more

Pd-catalyzed desulfonylative fluorination of electron-deficient (hetero)aryl sulfonyl fluorides

Chemical Science(2025)10.1039/d5sc00912j

N/A

0DataRank · unranked

1 citations

Natalie P. Romer, Taylor E. Spiller, Matthew S. Sigman, Melanie S. Sanford, Jonathan R. Hall

Enantioselective Synthesis of Complex Carbocycles by Donor/Donor Carbenes C-H insertion

ChemRxiv(2025)10.26434/chemrxiv-2025-b1fh6-v2

N/A

0DataRank · unranked

0 citations

Dylan Turner, Mingchun Gao, Wentao Guo, Tania Shahvali, Emily Jimenez +7 more

Low-Cost Mechanism-Informed Features Enable Transferable Enantioselectivity Predictions from Sparse Data

ChemRxiv(2025)10.26434/chemrxiv-2025-f5ddv

N/A

0DataRank · unranked

1 citations

Enrico Bucci, Abigail G. Doyle, Matthew S. Sigman, Simone Gallarati

Enantioselective Synthesis of Complex Carbocycles by Donor/Donor Carbenes C-H insertion

ChemRxiv(2025)10.26434/chemrxiv-2025-b1fh6

N/A

0DataRank · unranked

0 citations

Dylan Turner, Mingchun Gao, Wentao Guo, Tania Shahvali, Emily Jimenez +7 more

Enantioselective Allenoate-Claisen Rearrangement Using Chiral Phosphate Catalysts

Journal of the American Chemical Society(2020)10.1021/jacs.0c01637

N/A

0DataRank · unranked

70 citations

Tobias Gensch, Mario Ellwart, Seo‐Jung Han, Hsin‐Hui Lin, Matthew S. Sigman +2 more

Correction to “A Data Science-Guided Approach for the Development of Nickel-Catalyzed Homo-Diels–Alder Reactions”

Journal of the American Chemical Society(2025)10.1021/jacs.5c18763

N/A

0DataRank · unranked

0 citations

Cedric Lozano, Morgan T. Merriman, P.F. Oblad, Matthew S. Sigman, Sarah E. Reisman +1 more

Development and Mechanistic Interrogation of Interrupted Chain-Walking in the Enantioselective Relay Heck Reaction

Journal of the American Chemical Society(2020)10.1021/jacs.0c03589

N/A

0DataRank · unranked

67 citations

Ajara A. Rahman, Matthew S. Sigman, Sean P. Ross

Strategies for remote enantiocontrol in chiral gold( iii ) complexes applied to catalytic enantioselective γ,δ-Diels–Alder reactions

Chemical Science(2020)10.1039/d0sc00497a

N/A

0DataRank · unranked

60 citations

Mingyou Hu, Susumu Ito, Banruo Huang, Cynthia Hong, Hengye Xiang +3 more

Electrochemical Ruthenium-Catalyzed C–H Hydroxylation of Amine Derivatives in Aqueous Acid

Organic Letters(2020)10.1021/acs.orglett.0c01313

N/A

0DataRank · unranked

30 citations

James B. C. Mack, Sara N. Alektiar, J. Du Bois, Matthew S. Sigman, Sophia G. Robinson

Analyzing Mechanisms in Co(I) Redox Catalysis Using a Pattern Recognition Platform

ChemRxiv(2020)10.26434/chemrxiv.13017161

N/A

0DataRank · unranked

2 citations

Christopher Sandford, Shelley D. Minteer, Matthew S. Sigman, Tianhua Tang