The Role of Ylides in the Chlorination of Unsymmetrical Sulfides: An Ab Initio Molecular Orbital Study is a research paper published in Australian Journal of Chemistry (2005). On theSindex it has a DataRank of 0.149. It has been cited 1 time, with 1 citing works in its 1-hop citation network.
Ab initio molecular orbital theory has been used to investigate a series of possible chlorosulfonium ylides to assess the potential for ylide intermediacy in the chlorination of organic sulfides. The majority of optimized structures are best viewed as thionium salts. Only ylide structures in which the putative carbanionic centre bears a powerful anion stabilizer (e.g. cyano or carbomethoxy) survive optimization.
FAIR checklist signals are shown for context only and do not affect DataRank scoring.
Base Score Contribution
0.104
From this paper's citation signal
Citation Network Contribution
0.0447
From 1 citing papers with measurable signal
DataRank blends this paper's own citation count with the influence of the papers that cite it. Here, roughly 70% comes from its base citations and 30% from the citation network (1 citing paper contributed measurable signal).
Citers are pulled from OpenAlex sorted by cited_by_count:descand capped per paper, so when the cap binds we keep the highest-signal references and the score is reproducible across reruns.
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